The preposition " at "
CASE -1 time indicated in the sentence is sharp and precise.
Example
1) I have to catch the train
at 1 p.m.
2) Church close
at noon.
3) I would like to talk to you
at dinner time.
4) I love reading
at bedtime.
5) The best time to offer prayer is
at the sunrise or
at sunset.
6) The show starts
at 7.30 pm.
7) Its prohibited to go out
at midnight.
8) I will meet you
at the start of the match
note-'at't is used here with time of the day-sunrise,sunset,noon,midnight
CASE-2 at holidays or festivals
Example
1) I will go to home
at Diwali
2) Maria is too busy
at Christmas
CASE -3 at an age
Example
1) I would going to buy a car at an age of 18.
2) At 16, he joined his father's business.
CASE-4
at night
at the weekend
at the same time
at present
at any moment
The preposition "in"
used in a period(period of time/months/seasons/years/centuries)
Example
1)in 2 hrs.
2)in 4 days.
3)in February.
4) in summer
5)in 2011
6)in 20th century.
7)in the morning
8)in the afternoon
The preposition "on"
used for days/dates/special days
Example
1) on Monday.
2) on 29 August..
3) on Father's day.
4) on my birthday.
5) on Independence day eve.
6) on Monday morning